This thesis contains the research on the chemical composition of top horizons of soils originated from post-mining ground and selected rocks from the addition of brown coal. The analyzed soils originated from the mixture of the following additional sedimentary rocks of brown coal: glacial till (Würm), glacial till (Riss-grey till), sands and Poznan clays. Experimental factors were crop rotations (rape-grain and fodder) and three levels of mineral fertilization (0 NPK, 1 NPK and 2 NPK). The content of following elements was examined: Si, Al, Fe, Mn, Ca, K, Mg, Ti, Mn, Sr, Pb, Cd, Cr, Ni, Co, Zn, Cu. The total amount of all the listed elements was marked with two methods. The first was digestion method in HF with which the total amount of all the elements was determined, the latter was a method of extraction with aqua regia with which the content of elements close to the total was marked. The results proved that the mixture of the mentioned rocks has got impact on the properties of soils which originate from it. The average contents of the components determined in HF in g∙kg-1 were: Si-347,35; Sr-0,3; Ca-29,0; Al-24,2; Na-4,1; Mg-6,0; Fe-11,6; K-11,8; Mn-0,3; Ti-2,1 whereas macroelement in aqua regia in g∙kg-1: Sr-0,16; Ca-26,72; Al-9,78; Na-0,32; Mg-5,75; Fe-8,65; K-3,06; Mn-0,16; microelements Zn-25,87; Pb-3,6; Co-3,5; Cd-0,064; Cr-12,37; Ni-10,97; Cu-7,018. The amounts of various components differed in various extracts, yet the results were strictly correlated. Statistical analysis showed that graining of the originating soils was most similar to glacial till of Würm and Riss.